Neville belonged to a cadet branch of the same family as the earls of Westmorland. A younger son, in 1579 he married the daughter of Thomas Lewknor, a member of a prominent West Sussex family who represented Midhurst in 1586.
Neville may have sought election in 1604 to assist his elder brother, who claimed the barony of Bergavenny. The expenses incurred in pursuing the claim required a sale of lands, and in 1601 a private Act had been obtained to break the entail on the family estates. However, because a flaw had been found in the wording of the statute an explanatory Act was now needed. He presumably owed his return for Midhurst to his Lewknor relations, who were influential in the borough. In the 1604 session he was appointed to two committees (14 May; 14 June), both concerning the Neville estate bill. He may also have been the ‘Mr. Nevill’ on whose behalf Richard Martin offered a proviso to the bill for limitation of prescription on 24 April. However, no connection between Neville and the unsuccessful bill, which was intended to amend an early sixteenth century statute limiting the time within which suits could be brought, has been found. He made no recorded speeches.
Neville appears only twice in the surviving records of the remainder of the first Jacobean Parliament. In the second session he was appointed to the committee for the usury bill (3 Apr. 1606) and during the fourth he was named to consider a further bill to enable his brother to sell lands (7 July 1610).
